Copper(I) Complex [Cu(ca 2 dapte)(NCS)] with the Flexible N 2 S 2 Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure

Simple item page
dc.contributor.authorMorshedi, Mahbod
dc.contributor.authorAmirnasr, Mehdi
dc.contributor.authorTriki, Smail
dc.contributor.authorKhalaji, Aliakbar Dehno
dc.date.accessioned2015-12-07T22:46:55Z
dc.date.issued2011
dc.date.updated2016-02-24T11:43:17Z
dc.description.abstractNew copper(I) complex involving the flexible N2S2 Schiff-base ligand ca2dapte [Cu(ca2dapte)(NCS)], [ca 2dapte = N,N'-bis-(cinnamaldehyde)-1,2-di(o-iminophenylthio) ethane], has been synthesized and structurally characterized by X-ray diffraction analysis. The coordination polyhedron around the Cu(I) center is best described as a distorted tetrahedron. The flexible N2S2 Schiff-base ligand ca2dapte acts as a tridentate ligand via two S atoms and one N atom, while the NCS- ligand is coordinated to the metal ion through its nitrogen atom. Crystal data: space group P-1, a = 10.7486(7), b = 12.3737(13), c = 12.7578(11) Å, α = 89.385(7), β = 68.527(7), γ = 66.190(8)°; V = 1425.8(2) Å3, Z = 2, R = 0.0417, wR 2 = 0.0744.
dc.identifier.issn1074-1542
dc.identifier.urihttp://hdl.handle.net/1885/25983
dc.publisherKluwer Academic Publishers
dc.sourceJournal of Chemical Crystallography
dc.subjectKeywords: Copper (I) complex; N2S2 Schiff-base; Tridentate coordination mode; X-ray crystal structure
dc.titleCopper(I) Complex [Cu(ca 2 dapte)(NCS)] with the Flexible N 2 S 2 Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure
dc.typeJournal article
local.bibliographicCitation.issue1
local.bibliographicCitation.lastpage43
local.bibliographicCitation.startpage39
local.contributor.affiliationMorshedi, Mahbod, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationAmirnasr, Mehdi, Isfahan University of Technology
local.contributor.affiliationTriki, Smail, University of Bretagne Occidentale
local.contributor.affiliationKhalaji, Aliakbar Dehno, Gorgan University of Agricultural Sciences and Natural Resources
local.contributor.authoruidMorshedi, Mahbod, u4941454
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu8801298xPUB41
local.identifier.citationvolume41
local.identifier.doi10.1007/s10870-010-9833-4
local.identifier.scopusID2-s2.0-79951682973
local.identifier.thomsonID000285973600008
local.type.statusPublished Version

Downloads

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
01_Morshedi_Copper(I)_Complex_[Cu(ca_2_2011.pdf
Size:
251.98 KB
Format:
Adobe Portable Document Format
Download

Collections

ANU Research Publications

DSpace software copyright © 2002-2026 LYRASIS