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Undecacarbonyl(methylcyclopentadienyl)- tetrahedro -triiridiummolybdenum, undecacarbonyl(tetramethylcyclopentadienyl)- tetrahedro -triiridiummolybdenum and undecacarbonyl(pentamethylcyclopentadienyl)- tetrahedro -triiridiummolybdenum

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Date

2002

Authors

Lucas, Nigel
Whittall, Ian
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

Munksgaard International Publishers

Abstract

The crystal structure of the molybdenum organometallic compound complexes was studied. The alkyl cyclopentadienyl ligands provided flexibility in tuning the electronic and steric properties of the complex. The decreasing Mo-Co distances on increasing both steric bulk and electronic-donating properties of the alkylcyclopentadienyl ligands showed that electronic factors dominated over steric consideration of the ligand disposition.

Description

Keywords

Keywords: Chemical bonds; Complexation; Crystal structure; Molybdenum compounds; Tuning; Ligand disposition; Organometallics

Citation

URI

http://hdl.handle.net/1885/73386

Collections

ANU Research Publications

Source

Acta Crystallographica Section C: Crystal Structure Communications

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1107/S0108270101020558

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