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Sterically induced transmutations in cobalt amine chemistry

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Date

1999

Authors

Skelton, Brian
Qin, Chang
Ralph, Stephen
White, Allan
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to Co(III/II)N6 redox potentials close to +0.8 V (vs. SHE) and Co(II) hexaamine complexes that are air and substitution stable.

Description

Keywords

Keywords: amine; cobalt derivative; article; chemical structure; nuclear magnetic resonance spectroscopy; oxidation reduction potential; potentiometry; stereochemistry

Citation

URI

http://hdl.handle.net/1885/93783

Collections

ANU Research Publications

Source

Chemical Communications

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

Restricted until

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