Sterically induced transmutations in cobalt amine chemistry
Date
1999
Authors
Skelton, Brian
Qin, Chang
Ralph, Stephen
White, Allan
Willis, Anthony
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to Co(III/II)N6 redox potentials close to +0.8 V (vs. SHE) and Co(II) hexaamine complexes that are air and substitution stable.
Description
Keywords
Keywords: amine; cobalt derivative; article; chemical structure; nuclear magnetic resonance spectroscopy; oxidation reduction potential; potentiometry; stereochemistry
Citation
Collections
Source
Chemical Communications
Type
Journal article