Comparison of the Kinetics and Thermodynamics for Methyl Radical Addition to C=C, C=O, and C=S Double Bonds

Date

2004

Authors

Henry, David
Coote, Michelle
Gomez-Balderas, Rodolfo
Radom, Leo

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The barriers, enthalpies, and rate constants for the addition of methyl radical to the double bonds of a selection of alkene, carbonyl, and thiocarbonyl species (CH2=Z, CH3CH=Z, and (CH 3)2C=Z, where Z = CH2, O, or S) and for the reverse β-scission react

Description

Keywords

Keywords: Chemical bonds; Enthalpy; Mathematical models; Olefins; Phase transitions; Rate constants; Substrates; Contrathermodynamic reactions; Reaction barriers; Methanol; alkene; carbon; carbonyl derivative; methyl group; oxygen; radical; sulfur; thiocarbonyl der

Citation

Source

Journal of the American Chemical Society

Type

Journal article

Book Title

Entity type

Access Statement

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DOI

10.1021/ja039139a

Restricted until

2037-12-31