Comparison of the Kinetics and Thermodynamics for Methyl Radical Addition to C=C, C=O, and C=S Double Bonds
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Henry, David
Coote, Michelle
Gomez-Balderas, Rodolfo
Radom, Leo
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American Chemical Society
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The barriers, enthalpies, and rate constants for the addition of methyl radical to the double bonds of a selection of alkene, carbonyl, and thiocarbonyl species (CH2=Z, CH3CH=Z, and (CH 3)2C=Z, where Z = CH2, O, or S) and for the reverse β-scission react
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Journal of the American Chemical Society
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2037-12-31
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