Templated synthesis and intact coordination of a diorganotriselenane: [RuCl 2 (PPh 3 ){κ 3 - Se , N , N' -Se(mt Se ) 2 }] (mt Se = selenomethimazolyl)

Date

2006

Authors

Dewhurst, Rian
Hansen, Andrew
Hill, Anthony
Smith, Matthew

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The reaction of [RuCl2(PPh3)3] with methimazole (Hmt) under basic conditions provides the simple bis(chelate) complex [Ru(κ2-S,N-mt)2(PPh3) 2], while the selenium analogue HmtSe provides an intact coordinated diorganotriselenane [Ru{κ3-Se,N,N′-Se(mt S

Description

Keywords

Keywords: Complexation; Coordination reactions; Paraffins; Selenium compounds; Synthesis (chemical); Bidentate compounds; Diorganotriselenane; Methimazole; Organometallics

Citation

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om0608511

Restricted until

2037-12-31