Self-assembly of supramolecular platinum complexes with bis-4-pyridyl cavitands

Date

2006

Authors

Jude, Hershel
Sinclair, David
Das, Neeladri
Stang, Peter J
Sherburn, Michael

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The design and self-assembly of six new supramolecular complexes (four triangles and two 2+2 assemblies) are described. These assemblies incorporate two new bispyridyl cavitand building blocks and were prepared in excellent yields (85-95%). The assemblies and building blocks were characterized with multinuclear NMR spectroscopy, electrospray ionization mass spectrometry, and elemental analysis. Isotopically resolved mass spectrometry along with NMR data confirms the existence of the six assemblies.

Description

Keywords

Keywords: Electrospray ionization mass spectrometry; Elemental analysis; Supramolecular platinum complexes; Complexation; Ionization; Mass spectrometry; Nuclear magnetic resonance spectroscopy; Platinum; Self assembly; Supramolecular chemistry; c pentyl a,c dibromo

Citation

Source

Journal of Organic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/jo060133o

Restricted until

2037-12-31