The nature of species derived from [Pt(bipy) 2 ] 2+  in aqueous solution: X-ray structural, mass spectral, NMR, and computational studies

Cavigliasso, German; Stranger, Robert; Lo, Warrick K.C.; Crowley, James D.; Blackman, Allan G.

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The nature of species derived from [Pt(bipy) 2 ] 2+ in aqueous solution: X-ray structural, mass spectral, NMR, and computational studies

Date

2013

Authors

Cavigliasso, German

Stranger, Robert

Lo, Warrick K.C.

Crowley, James D.

Blackman, Allan G.

Publisher

Pergamon-Elsevier Ltd

Abstract

The reaction of [Pt(bipy)2]2+ with a variety of organic and inorganic ligands in aqueous solution has been studied by 195Pt, 1H and 13C NMR, X-ray crystallography, UV-Vis spectroscopy and high-resolution mass spectrometry. 195Pt NMR spectra of D2O solutio