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Synthesis and interconversions of digold(I), tetragold(I), digold(II), gold(I)-gold(III) and digold(III) complexes of fluorine-substituted aryl carbanions

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dc.contributor.authorBennett, Martin
dc.contributor.authorBhargava, Suresh Kumar
dc.contributor.authorMirzadeh, Nedaossadat
dc.contributor.authorPriver, Steven H
dc.contributor.authorWagler, Jorg
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-10T22:31:59Z
dc.date.issued2009
dc.date.updated2016-02-24T10:23:09Z
dc.description.abstractTreatment of [AuXL] (X = Br, L = AsPh3; X = Cl, L = tht) with the lithium or trimethyltin derivatives of the carbanions [2-C6F 4PPh2]- and [C6H3-n-F-2- PPh2]- (n = 5, 6) gives digold(i) complexes [Au 2(μ-carbanion)2] (carbanion = 2-C6F 4PPh22, C6H3-5-F-2
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/55576
dc.publisherRoyal Society of Chemistry
dc.sourceDalton Transactions
dc.subjectKeywords: Anation; Aurophilic interaction; Axial ligand; C-C coupling; Cyclohexanol; Dimethylzinc; Diphenylphosphine; Electronic effects; Interconversions; Isomerisation; Metal atoms; Oxidative additions; Oxyanions; Recrystallisation; Reductive elimination; Single
dc.titleSynthesis and interconversions of digold(I), tetragold(I), digold(II), gold(I)-gold(III) and digold(III) complexes of fluorine-substituted aryl carbanions
dc.typeJournal article
local.bibliographicCitation.lastpage7551
local.bibliographicCitation.startpage7537
local.contributor.affiliationBennett, Martin, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBhargava, Suresh Kumar, RMIT University
local.contributor.affiliationMirzadeh, Nedaossadat, RMIT University
local.contributor.affiliationPriver, Steven H, RMIT University
local.contributor.affiliationWagler, Jorg, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidBennett, Martin, u6700468
local.contributor.authoruidWagler, Jorg, v006707
local.contributor.authoruidWillis, Anthony, u8512028
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationu4005981xPUB333
local.identifier.citationvolume36
local.identifier.doi10.1039/b906769h
local.identifier.scopusID2-s2.0-69949182738
local.identifier.thomsonID000269493900029
local.type.statusPublished Version

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