Chemistry of Cu deposition by Cu(hfac)(tmvs) monitored by Li⁺ ion attachment mass spectrometry
| dc.contributor.author | Fujii, Toshihiro | |
| dc.contributor.author | Arulmozhiraja, Sundaram | |
| dc.contributor.author | Nakamura, Megumi | |
| dc.contributor.author | Shiokawa, Yoshiro | |
| dc.date.accessioned | 2015-11-27T04:55:03Z | |
| dc.date.available | 2015-11-27T04:55:03Z | |
| dc.date.issued | 2006-10-31 | |
| dc.description.abstract | Ion attachment mass spectrometry was used for continuous in situanalysis of coordinated products formed during copperchemical vapor deposition(CuCVD) by Cu(1,1,1,5,5,5-hexafluoroacetylacetonate)(vinyltrimethylsilane) [Cu(hfac)(tmvs)] in a simple tubular reactor. This study of the thermally labile Cu(hfac)(tmvs) demonstrated the utility of this method for detecting molecular ions of labile compounds. The results demonstrate the feasibility of monitoring the deposition chemistry of Cu(hfac)(tmvs) by generating Li⁺ adduct molecular ions by means of the Li⁺ ion attachment technique. The reaction pathways for CuCVD by Cu(hfac)(tmvs) were studied by analysis of the reaction products. H(hfac) and tmvs were identified as the main products when Cu(hfac)tmvs was heated at temperatures ranging from room temperature to 160°C in the reactor. The rate constant for Cu deposition, k (1/s), was determined to be 1.6×10⁶exp(−10.2kcal/molRt). | en_AU |
| dc.description.sponsorship | This work was supported in part by The New Energy and Industrial Technology Development Organization NEDO under a fund for Fundamental Technology Research Facilitation Program. | en_AU |
| dc.identifier.issn | 0021-8979 | en_AU |
| dc.identifier.uri | http://hdl.handle.net/1885/16887 | |
| dc.publisher | American Institute of Physics (AIP) | en_AU |
| dc.rights | http://www.sherpa.ac.uk/romeo/issn/0021-8979..."Publishers version/PDF may be used on author's personal website, institutional website or institutional repository" from SHERPA/RoMEO site (as at 27/11/15). Copyright 2006 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Journal of Applied Physics and may be found at https://doi.org/10.1063/1.2360768 | en_AU |
| dc.source | Journal of Applied Physics | en_AU |
| dc.title | Chemistry of Cu deposition by Cu(hfac)(tmvs) monitored by Li⁺ ion attachment mass spectrometry | en_AU |
| dc.type | Journal article | en_AU |
| local.bibliographicCitation.issue | 8 | en_AU |
| local.bibliographicCitation.startpage | 084912 | en_AU |
| local.contributor.affiliation | Fujii, Toshihiro, Meisei University, Japan | en_AU |
| local.contributor.affiliation | Arulmozhiraja, Sundaram, College of Physical and Mathematical Sciences, CPMS Research School of Chemistry, RSC General, The Australian National University | en_AU |
| local.contributor.affiliation | Nakamura, Megumi, Canon Anelva Texnix Corporation, Japan | en_AU |
| local.contributor.affiliation | Shiokawa, Yoshiro, Canon Anelva Texnix Corporation, Japan | en_AU |
| local.contributor.authoruid | u4633119 | en_AU |
| local.description.notes | Imported from ARIES. At the time of publication the author Arulmozhiraja was affiliated with Environmental Chemistry Division, National Institute for Environmental Studies, Japan | en_AU |
| local.identifier.absfor | 030701 | en_AU |
| local.identifier.ariespublication | U4217927xPUB656 | en_AU |
| local.identifier.citationvolume | 100 | en_AU |
| local.identifier.doi | 10.1063/1.2360768 | en_AU |
| local.publisher.url | https://www.aip.org/ | en_AU |
| local.type.status | Published Version | en_AU |