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Highly Functionalized Five-Membered Carbocycles from (3-Dialkylamino-1-ethoxyalkenylidene)pentacarbonylchromium Complexes and Alkynes: The Effects of Substituents, Solvents, Ligand Additives, and Reagent Concentrations on the Product Distribution

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Date

2001

Authors

Flynn, Bernard
Schirmer, Heiko
Duetsch, Michael
de Meijere, Armin

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The cocyclization reaction of pentacarbonyl(β-amino-1-ethoxyalkenylidene)chromium complexes I with alkynes has been studied with respect to the effects of substituents, solvents, ligand additives, and reagent concentrations upon the product distribution.

Description

Keywords

Keywords: alkyne; chromium derivative; pentacarbonylchromium; reagent; unclassified drug; article; chemical reaction; complex formation; cyclization; hydrolysis; ligand binding; proton nuclear magnetic resonance; reaction analysis

Citation

URI

http://hdl.handle.net/1885/94025

Collections

ANU Research Publications

Source

Journal of Organic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/jo005708a

Restricted until

2037-12-31

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01_Flynn_Highly_Functionalized_2001.pdf (99.79 KB)

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