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Bis(acetylacetonato)ruthenium(II) complexes containing alkynyldiphenylphosphines. Formation and redox behavior of [Ru(acac) 2 (Ph 2 PC≡CR) 2 ] (R = H, Me, Ph) complexes and the binuclear complex cis -[{Ru(acac) 2 } 2 (μ-Ph 2 PC≡CPPh 2 )} 2 ]

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dc.contributor.authorBennett, Martin
dc.contributor.authorByrnes, Matthew
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-08T22:08:24Z
dc.date.issued2007
dc.date.updated2015-12-08T07:17:07Z
dc.description.abstractTwo equivalents of Ph2PCCR (R = H, Me, Ph) react with thf solutions of cis-[Ru(acac)2(η2-alkene)2] (acac = acetylacetonato; alkene = C2H4, 1; C 8H14, 2) at room temperature to yield the orange, air-stable compounds trans-[Ru(acac)2(Ph2PCCR) 2] (R = H, tr
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/28598
dc.publisherRoyal Society of Chemistry
dc.sourceDalton Transactions
dc.subjectKeywords: Electrochemistry; Phosphorus compounds; Redox reactions; Ultraviolet spectroscopy; X ray crystallography; Alkynyldiphenylphosphines; Bis(acetylacetonato)ruthenium(ii) complexes; Comproportionation constant; Ruthenium compounds
dc.titleBis(acetylacetonato)ruthenium(II) complexes containing alkynyldiphenylphosphines. Formation and redox behavior of [Ru(acac) 2 (Ph 2 PC≡CR) 2 ] (R = H, Me, Ph) complexes and the binuclear complex cis -[{Ru(acac) 2 } 2 (μ-Ph 2 PC≡CPPh 2 )} 2 ]
dc.typeJournal article
local.bibliographicCitation.issue17
local.bibliographicCitation.lastpage1686
local.bibliographicCitation.startpage1977
local.contributor.affiliationBennett, Martin, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationByrnes, Matthew, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidBennett, Martin, u6700468
local.contributor.authoruidByrnes, Matthew, u960490
local.contributor.authoruidWillis, Anthony, u8512028
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor030604 - Electrochemistry
local.identifier.ariespublicationu4005981xPUB59
local.identifier.citationvolume2007
local.identifier.doi10.1039/b618365d
local.identifier.scopusID2-s2.0-34247335876
local.type.statusPublished Version

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