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Which side-reactions compromise nitroxide mediated polymerization?

Date

Authors

Gryn'ova, Ganna

Lin, Ching-Yeh

Coote, Michelle

Publisher

Wiley-VCH Verlag GMBH

Abstract

The mechanism of the nitroxide mediated polymerization (NMP) is well understood, however less is known about the side-reactions that interfere and in certain cases severely compromise it. Experimental studies inevitably involve model fitting leading to at

Keywords

Keywords: Disproportionations; Experimental datum; Experimental studies; Kinetic simulation; Methacrylate monomers; Nitroxide mediated polymerization; Polymerization conditions; Quantum-chemical calculation; Decomposition; Equilibrium constants; Quantum chemistry;

URI

http://hdl.handle.net/1885/72946

Collections

ANU Research Publications

Source

Journal of Polymer Science: Part A: Polymer Chemistry

Type

Journal article

DOI

10.1039/c3py00534h

Restricted until

2037-12-31

Downloads

File

Description

01_Gryn'ova_Which_side-reactions_2013.pdf (1.13 MB)