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Estimation of standard reduction potentials of halogen atoms and alkyl halides

Date

Authors

Isse, Abdirisak A

Lin, Ching-Yeh

Coote, Michelle

Gennaro, Armando

Publisher

American Chemical Society

Abstract

Standard reduction potentials, SRPs, of the halogen atoms have been calculated in water on the basis of an appropriate thermochemical cycle. Using the best up-to-date thermodynamic data available in the literature, we have calculated EX/X⊖ - values of 3

Keywords

Keywords: Alkyl halides; Gasphase; Halogen atoms; Homolytic dissociation; Non-aqueous solvents; Pollution abatement; Standard reduction potentials; Thermochemical cycles; Thermodynamic data; Acetonitrile; Alkylation; Atoms; Bromine; Chlorine; Dimethylformamide; Fre

URI

http://hdl.handle.net/1885/58385

Collections

ANU Research Publications

Source

Journal of Physical Chemistry B

Type

Journal article

DOI

10.1021/jp109613t

Restricted until

2037-12-31

Downloads

File

Description

01_Isse_Estimation_of_standard_2011.pdf (135.52 KB)