1,3,5-Triaryl-1,3,5-Triazinane-2,4,6-Trithiones: Synthesis, Electronic Structure and Linear Optical Properties

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dc.contributor.authorRabouel, Ismaël
dc.contributor.authorRichy, Nicolas
dc.contributor.authorAmar, Anissa
dc.contributor.authorBoucekkine, Abdou
dc.contributor.authorRoisnel, Thierry
dc.contributor.authorMongin, Olivier
dc.contributor.authorHumphrey, Mark
dc.contributor.authorPaul, Frederic
dc.date.accessioned2022-08-01T23:20:51Z
dc.date.available2022-08-01T23:20:51Z
dc.date.issued2020
dc.date.updated2021-08-01T08:24:48Z
dc.description.abstractThe synthesis of four new 1,3,5-triaryl-1,3,5-triazinane-2,4,6-trithione derivatives (thioisocyanurates) and two new partially thionated analogues from the corresponding 1,3,5-triaryl-1,3,5-triazinane-2,4,6-triones (isocyanurates) is reported, together with their spectroscopic properties. DFT calculations and comparison with the corresponding isocyanurates evidence the impact of the oxygen-for-sulfur replacement on the electronic structure and linear optical properties of these heterocycles. A bathochromic shift of the absorption bands and more efficient quenching of the fluorescence was observed.en_AU
dc.description.sponsorshipThis project was supported by ANR (ANR-17-CE07-0033-01 project).en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1420-3049en_AU
dc.identifier.urihttp://hdl.handle.net/1885/270086
dc.language.isoen_AUen_AU
dc.provenanceThis article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).en_AU
dc.publisherMolecular Diversity Preservation Internationalen_AU
dc.rights© 2020 by the authors. Licensee MDPI, Basel, Switzerland.en_AU
dc.rights.licenseCreative Commons Attribution (CC BY) licenseen_AU
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en_AU
dc.sourceMoleculesen_AU
dc.subjectthioisocyanuratesen_AU
dc.subjectisocyanuratesen_AU
dc.subjectthionationen_AU
dc.subjectDFT calculationsen_AU
dc.subjectcyclic thioureasen_AU
dc.subjectlinear opticsen_AU
dc.subjectcyclic ureaen_AU
dc.title1,3,5-Triaryl-1,3,5-Triazinane-2,4,6-Trithiones: Synthesis, Electronic Structure and Linear Optical Propertiesen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Accessen_AU
local.bibliographicCitation.issue22en_AU
local.bibliographicCitation.lastpage17en_AU
local.bibliographicCitation.startpage1en_AU
local.contributor.affiliationRabouel, Ismaël, Université de Rennesen_AU
local.contributor.affiliationRichy, Nicolas, Université de Rennesen_AU
local.contributor.affiliationAmar, Anissa, Universite Mouloud Mammerien_AU
local.contributor.affiliationBoucekkine, Abdou, Universite de Rennesen_AU
local.contributor.affiliationRoisnel, Thierry, Universite de Rennesen_AU
local.contributor.affiliationMongin, Olivier, Universite Rennesen_AU
local.contributor.affiliationHumphrey, Mark, College of Science, ANUen_AU
local.contributor.affiliationPaul, Frederic, Universite de Rennesen_AU
local.contributor.authoremailu9400918@anu.edu.auen_AU
local.contributor.authoruidHumphrey, Mark, u9400918en_AU
local.description.notesImported from ARIESen_AU
local.identifier.absfor340304 - Optical properties of materialsen_AU
local.identifier.absfor340503 - Organic chemical synthesisen_AU
local.identifier.ariespublicationa383154xPUB16041en_AU
local.identifier.citationvolume25en_AU
local.identifier.doi10.3390/molecules25225475en_AU
local.identifier.scopusID2-s2.0-85096817652
local.identifier.uidSubmittedBya383154en_AU
local.publisher.urlhttp://www.mdpi.com/journal/moleculesen_AU
local.type.statusPublished Versionen_AU

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