Organometallic Complexes for Nonlinear Optics. 43. Quadratic Optical Nonlinearities of Dipolar Alkynylruthenium Complexes with Phenyleneethynylene/Phenylenevinylene Bridges

Rigamonti, Luca; Babgi, Bandar; Cifuentes, Marie; Roberts, Rachel; Petrie, Simon; Stranger, Robert; Righetto, Stefania; Teshome, Ayele; Asselberghs, Inge; Clays, Koen Jan; Humphrey, Mark

Organometallic Complexes for Nonlinear Optics. 43. Quadratic Optical Nonlinearities of Dipolar Alkynylruthenium Complexes with Phenyleneethynylene/Phenylenevinylene Bridges

Date

2009

Authors

Rigamonti, Luca

Babgi, Bandar

Cifuentes, Marie

Roberts, Rachel

Petrie, Simon

Stranger, Robert

Righetto, Stefania

Teshome, Ayele

Asselberghs, Inge

Clays, Koen Jan

Publisher

American Chemical Society

Abstract

The syntheses of trans-[Ru(4,4′-C≡CC6H 4C≡CC6H4NO2)Cl(dppe) 2] (19) and the systematically varied complexes trans-[Ru(4,4′, 4′′-C≡CC6H4X2C 6H4Y2C6H4NO 2)Cl(L2)2] [L2 = dppe, X2 = C≡C, Y2 = (E)-CH=CH (12), C≡C (18); L2 = dppe, X2 = (E)-CH