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Packing and polytypism in 1,10-phenanthrolin-1-ium (2-carboxyethyl)(2-carboxylatoethyl)dichlorostannate(IV)

Date

Authors

Somphon, Weenawan

Haller, Kenneth J

Rae, A David

Ng, Seik Weng

Publisher

Munksgaard International Publishers

Abstract

The 1:1 adduct of [SnCl2(C2H4COOCH 3] and 1,10-phenanthroline, (C12H8N 2), which was set aside for 25 years, when recrystallized from ethanol was found to be the salt [C12H9N2] +·[SnCl2(C2H4COO)(C 2H4COOH)]-. The SnIV atom in the anion has pseudo-octahed

Keywords

Keywords: Carboxylation; Chlorine; Ethanol; Hydrogen bonds; Negative ions; Recrystallization (metallurgy); Salts; Carboxylatoethyl; Cl interactions; Octahedral coordination; Polytypism; Esters

URI

http://hdl.handle.net/1885/83552

Collections

ANU Research Publications

Source

Acta Crystallographica Section B: Structural Science

Type

Journal article

DOI

10.1107/S0108768106002461

Restricted until

2037-12-31

Downloads

File

Description

01_Somphon_Packing_and_polytypism_in_2006.pdf (290.07 KB)