A triad of bis(orthometalated) d 8 -complexes containing four-membered rings
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Bennett, Martin
Bhargava, Suresh Kumar
Keniry, Max
Priver, Steven H
Simmonds, Peta
Wagler, Jorg
Willis, Anthony
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American Chemical Society
Abstract
Reaction of 2-LiC6F4PPh2 with [MCl 2(SEt2)2] in diethyl ether gives the monomeric bis(chelate) complexes trans-[M((κ2-2-C6F 4PPh2)2] [M = Pt (1), Pd (2)] or, in the case of platinum, a mixture of cis-and trans-isomers. Treatment of a mixture of NiCl2 and
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Organometallics
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2037-12-31