Iridium tricarbido complexes via transmetallation with tricarbidomercurials

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Dewhurst, Rian
Hill, Anthony
Willis, Anthony

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Royal Society of Chemistry

Abstract

The reactions of Vaska's complex with [Hg{CCCW(CO)2(L)} 2] (L = HB(pz)3, HB(pzMe2)3, pz = pyrazol-1-yl) unexpectedly provide the structurally characterized tetrametallic trans-bis(tricarbido)complex [Ir(HgCl){CCCW(CO)2(L)} 2(CO)(PPh3)2].

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Dalton Transactions

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Restricted until

2037-12-31