Trigonal prismatic metal complexes: a not so rare coordination geometry?

Alcock, Leighton J.; Cavigliasso, German; Willis, Anthony C.; Stranger, Robert; Ralph, Stephen F.

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Trigonal prismatic metal complexes: a not so rare coordination geometry?

Date

2016

Authors

Alcock, Leighton J.

Cavigliasso, German

Willis, Anthony C.

Stranger, Robert

Ralph, Stephen F.

Publisher

Royal Society of Chemistry

Abstract

The solid state structures of two metal complexes of a hexaamine macrobicyclic ligand, in which the metal ion has an exact trigonal prismatic geometry, have been determined. Theoretical calculations showed this is the most stable geometry for d⁰, d¹⁰ and high spin d⁵ metal complexes of the ligand with M–N bond distances >∼2.35 Å.

URI

http://hdl.handle.net/1885/108630

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ANU Research Publications

Source

Dalton Transactions

Type

Journal article

Access Statement

Open Access

DOI

10.1039/C6DT01176D

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01_Alcock_Trigonal_Prismatic_2016.pdf (686.8 KB)

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Trigonal prismatic metal complexes: a not so rare coordination geometry?

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