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Mixed-Metal Cluster Chemistry. 22. Synthesis and Crystallographic, Electrochemical, and Theoretical Studies of Alkyne-Coordinated Group 6-Iridium Clusters Linked by Phenyleneethynylene Groups

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Date

2003

Authors

Lucas, Nigel
Notaras, Eleni
Petrie, Simon
Stranger, Robert
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

Reaction between the tetrahedral cluster compound Mo2Ir2(CO)10(η5-C5 H4Me)2 (1) and 1-iodo-4-(oct-1′-ynyl)benzene afforded the pseudooctahedral cluster Mo2Ir2 {μ4-η2-Me(CH2)5 C2-4-C6 H4I}(CO)8 (η5-C5H4Me)2 (7). Similar reactions of 1 and W2Ir2(CO)10

Description

Keywords

Keywords: Iridium clusters; Mixed metal cluster chemistry; Phenyleneethynylene groups; Crystallography; Cyclic voltammetry; Electrochemistry; Iridium compounds; Isomers; Numerical analysis; Oxidation; Probability density function; Reduction; Single crystals; Synthe

Citation

URI

http://hdl.handle.net/1885/76273

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om020910k

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