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Local Crystal Chemistry, Induced Strain and Short Range Order in the Cubic Pyrochlore (Bi1.5-αZn0.5-β)(Zn0.5-γNb1.5-δ)O7-1.5α-β-γ-2.5δ) (BZN)

Date

Authors

Withers, Raymond

Welberry, Thomas

Larsson, Ann-Kristin

Liu, Yun

Noren, Lasse

Rundlof, H

Brink, Frank

Publisher

Academic Press

Abstract

Clear evidence (in the form of structured diffuse scattering) is found for short range ordering of metal ions and associated induced structural relaxation in two members of the cubic BZN pyrochlore (Bi1.5-αZn 0.5-β)(Zn0.5-γNb1.5-δ)O (7-1.5α-β-γ-2.5

Keywords

Keywords: Crystal structure; Diffusion; Monte Carlo methods; Neutron scattering; Positive ions; Scattering; Stoichiometry; Electron probe micro-analysis; Bismuth compounds; bismuth derivative; metal ion; niobium; nonstoichiometric compound; zinc derivative; article Local mutation ordering; Monte Carlo modelling; Structured diffuse scattering

URI

http://hdl.handle.net/1885/86951

Collections

ANU Research Publications

Source

Journal of Solid State Chemistry

Type

Journal article

DOI

10.1016/j.jssc.2003.07.005

Restricted until

2037-12-31

Downloads

File

Description

01_Withers_Local_Crystal_Chemistry,_2004.pdf (799.13 KB)

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