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Molecular fibers and wires in solid-state and solution self-assemblies of cyclodextrin [2]rotaxanes

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Authors

Maniam, Subashani
Cieslinski, Marta
Lincoln, Stephen F
Onagi, Hideki
Steel, Peter J
Willis, Anthony
Easton, Christopher

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American Chemical Society

Abstract

Cyclodextrin [2]rotaxanes have been prepared by coupling dimethylanilines with dicarboxylic acids using DMT-MM. in aqueous solutions of a-cyclodextrin, and the example illustrated shows unusual fluorescence emission and other spectroscopic behavior characteristic of the formation of molecular wires in solution, similar to the fibers observed in the solid state.

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Organic Letters

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Restricted until

2037-12-31