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Reactions of ruthenium(0) phosphine complexes with diphenylacetylene

Date

Authors

Hill, Anthony

Schultz, Madeleine

Willis, Anthony

Publisher

American Chemical Society

Abstract

Heating diphenylacetylene with [Ru(CO)2(PPh3) 3] in toluene under reflux provides the 2-phenylindenone complex [Ru(η3=CCPh=CHC6H4)(CO)(PPh 3)2], arising from C-H activation of one ortho-proton of diphenylacetylene, hydroruthenation of the triple bond, an

Keywords

Keywords: Chemical bonds; Crystal structure; Nuclear magnetic resonance spectroscopy; Organometallics; Phenols; Thermal effects; Toluene; Ligands; Solvates; Starting materials; Thermal conditions; Reaction kinetics

URI

http://hdl.handle.net/1885/86803

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

DOI

10.1021/om0400954

Restricted until

2037-12-31

Downloads

File

Description

01_Hill_Reactions_of_ruthenium(0)_2004.pdf (181.19 KB)