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Mixed-Metal Cluster Chemistry. 30. 1 Syntheses and Optical Limiting Properties of Cluster-Containing Oligo- and Polyurethanes

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Randles , Michael
Lucas, Nigel
Cifuentes, Marie
Smith, Matthew
Willis, Anthony
Samoc, Marek
Humphrey, Mark

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American Chemical Society

Abstract

Molybdenum - iridium clusters Mo2Ir2{μ 4-η2-C2[(CH2) 6OH]2}(μ-CO)4(CO)4(η-C 5H4R)2 [R = H (5), Me (6), (CH 2)9O(THP) (7); THP = tetrahydropyranyl] are formed from reaction of Mo2Ir2(μ-CO)3(CO) 7(η-C5H4R)2 with the alkyne HO(CH2)6C2(CH2)6OH. Reaction

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Macromolecules

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Restricted until

2037-12-31
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