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Mixed-metal cluster chemistry. 31. Reactions of dimolybdenum-diiridium clusters with alkylidyne complexes

Date

Authors

Randles , Michael

Dewhurst, Rian

Cifuentes, Marie

Humphrey, Mark

Publisher

American Chemical Society

Abstract

Reactions of the tetrahedral clusters Mo2Ir2(μ-CO)3(CO)7(η5-L)2 (L = C5H5, C5HMe4) with the molybdenum alkylidyne complex Mo(≡CC6H4OMe-4)(CO)2{(N2C3H3)3BH- κ3N,N′,N″} afford the pentanuclear clusters Mo3Ir2(μ4-C)(μ3-CC6H4OMe-4)(μ-O)(CO)6{(N2C3

Keywords

Keywords: Alkylidynes; C-O cleavage; CO ligands; Mixed metal clusters; Pentanuclear clusters; Single crystal x-ray diffraction; Tetrahedral clusters; Acetylene; Iridium; Ligands; Molybdenum compounds; Tungsten; Tungsten compounds; X ray diffraction; Molybdenum

URI

http://hdl.handle.net/1885/62770

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

DOI

10.1021/om201053s

Restricted until

2037-12-31

Downloads

File

Description

01_Randles _Mixed-metal_cluster_chemistry._2012.pdf (488.25 KB)