Swift heavy ion irradiation of cobalt nanoparticles

Abstract

It is well known that the electronic energy loss released by swift heavy ions can cause considerable atomic movement in various solids. Here, we present a study of the effects of swift heavy ion irradiation on Co nanoparticles embedded within a silica host matrix. The evolution of the Co nanoparticle crystal phase, structural properties, shape and size has been characterized using a combination of x-ray absorption spectroscopy and transmission electron microscopy. An FCC-to-HCP phase transformation is observed at low fluences, while higher fluences result in significant changes in the short range order and NP shape. After an incubation fluence the nanoparticles deform into ellipsoids, preferentially aligned parallel to the incident beam direction. The threshold diameter for elongation was comparable to the saturation value of the ellipsoid width. We correlate this saturation value with the diameter of the molten track induced in amorphous silica by swift heavy ion irradiation.