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Electrocyclic processes in aromatic biosynthesis: a biomimetic study of pseudorubrenoic acid A.

Date

Authors

Rickards, Rodney

Skropeta, Danielle

Publisher

Elsevier

Abstract

The possible involvement of 6π electrocyclic ring closures, mediated by electrocyclase enzymes, of polyunsaturated acyclic polyketide intermediates in the biosynthesis of certain o-dialkyl-substituted benzenoid natural products is discussed. The feasibil

Keywords

Keywords: 1 (but 1' enyl) 2 (6'' tert butyldimethylsilyloxyhexyl)benzene; 1 tert butyldimethylsilyloxyhexadeca 7,9,11,13 tetraene; 5 (but 1' enyl) 6 (6'' tert butyldimethylsilyloxyhexyl)cyclohexa 1,3 diene; alkadiene; alkyl group; aromatic compound; benzene derivat Biomimetic synthesis; Biosynthesis; Electrocyclase; Electrocyclic reactions; Pseudorubrenoic acid

URI

http://hdl.handle.net/1885/91876

Collections

ANU Research Publications

Source

Tetrahedron

Type

Journal article

DOI

10.1016/S0040-4020(02)00320-4

Restricted until

2037-12-31

Downloads

File

Description

01_Rickards_Electrocyclic_processes_in_2002.pdf (157.79 KB)