Arsolyl-supported intermetallic dative bonding

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Kirk, Ryan
Hill, Anthony

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Royal Society of Chemistry

Abstract

The first examples of late transition metal η5-arsolyls (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R' = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional As → M and polar-covalent (dative) Co → M interactions.

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Chemical science

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Open Access

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Creative Commons Attribution 3.0 Unported Licence

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