Arsolyl-supported intermetallic dative bonding
Date
2022-06-15
Authors
Kirk, Ryan
Hill, Anthony
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Royal Society of Chemistry
Abstract
The first examples of late transition metal η5-arsolyls (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R' = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional As → M and polar-covalent (dative) Co → M interactions.
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Chemical science
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