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Organometallic complexes for nonlinear optics. Part 27. Syntheses and optical properties of some iron, ruthenium and osmium alkynyl complexes

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Date

2003

Authors

Powell, Clem
Cifuentes, Marie
McDonagh, Andrew
Hurst, Stephanie
Lucas, Nigel
Delfs, Christopher
Stranger, Robert
Houbrechts, Stephan
Asselberghs, Inge
Persoons, Andre Pierre

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier

Abstract

The syntheses of the alkynyl complexes M(4-C≡CC6H4NO2)(dppe)(η-C 5H5) [M=Fe (1), Ru (2), Os (3)], Os(4-C≡CC6H4NO2)(PPh3) 2(η-C5H5) (4) and Ru(4-C≡CC6H4NO2)(CO)2 (η-C5H5) (5) are reported. Structural studies reveal a decrease in Ru-C(1) distance o

Description

Keywords

Keywords: alkynyl group; biphenyl; carbonyl derivative; iron complex; ligand; metal; organometallic compound; osmium derivative; phosphine derivative; ruthenium complex; analytic method; article; calculation; chemical model; chemical structure; crystallography; dat Alkynyl; Cyclic voltammetry; Density functional theory; Iron; NLO; Osmium; Ruthenium; X-ray structure

Citation

URI

http://hdl.handle.net/1885/87674

Collections

ANU Research Publications

Source

Inorganica Chimica Acta

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1016/S0020-1693(03)00126-9

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