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High-nuclearity ruthenium carbonyl cluster chemistry. 8: Phosphine activation, CO insertion, and deruthenation at a phosphido cluster - X-ray structures of [ppn][Ru 8 (μ 8 -P)(μ-CO) 2 (CO) 20 ] and [ppn][Ru 7 (μ 7 -P)(μ-η 2 -OCPh)(μ-PPh 2 )(μ-CO) (CO) 17 ]

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dc.contributor.authorRandles , Michael
dc.contributor.authorWillis, Anthony
dc.contributor.authorCifuentes, Marie
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-08T22:48:07Z
dc.date.issued2007
dc.date.updated2015-12-08T11:03:46Z
dc.description.abstractReaction of the square antiprismatic cluster [ppn][Ru8(μ8-P)(μ-CO)2(CO)20] [ppn = bis(triphenylphosphoranylidene)ammonium] with triphenylphosphine proceeds by loss of one cluster core vertex, phosphine P-C cleavage, and CO insertion into the putative Ru
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/1885/38216
dc.publisherElsevier
dc.sourceJournal of Organometallic Chemistry
dc.subjectKeywords: Ammonium compounds; Carbon monoxide; Cluster analysis; Crystal structure; Antiprismatic cluster; Deruthenation; X-ray structures; Ruthenium compounds Cluster; Crystal structure; Interstitial; Phosphido; Ruthenium
dc.titleHigh-nuclearity ruthenium carbonyl cluster chemistry. 8: Phosphine activation, CO insertion, and deruthenation at a phosphido cluster - X-ray structures of [ppn][Ru 8 (μ 8 -P)(μ-CO) 2 (CO) 20 ] and [ppn][Ru 7 (μ 7 -P)(μ-η 2 -OCPh)(μ-PPh 2 )(μ-CO) (CO) 17 ]
dc.typeJournal article
local.bibliographicCitation.issue21
local.bibliographicCitation.lastpage4472
local.bibliographicCitation.startpage4467
local.contributor.affiliationRandles , Michael , College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCifuentes, Marie, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidRandles , Michael , u3956935
local.contributor.authoruidWillis, Anthony, u8512028
local.contributor.authoruidCifuentes, Marie, u9410034
local.contributor.authoruidHumphrey, Mark, u9400918
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4005981xPUB159
local.identifier.citationvolume692
local.identifier.doi10.1016/j.jorganchem.2007.03.040
local.identifier.scopusID2-s2.0-34548532705
local.type.statusPublished Version

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