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Diffusion-controlled chronoamperometry at a disk electrode

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dc.contributor.authorMahon, Peter
dc.contributor.authorOldham, Keith
dc.date.accessioned2015-12-13T22:45:21Z
dc.date.issued2005
dc.date.updated2015-12-11T10:21:06Z
dc.description.abstractAn accurate formula exists for describing the decay of the current following the imposition of extreme concentration polarization on a disk electrode under diffusion-controlled conditions. It has been amply validated by diverse simulations and is presented here in a more compact form than hitherto. The formula finds application beyond the realm of potential-step chronoamperometry.
dc.identifier.issn0003-2700
dc.identifier.urihttp://hdl.handle.net/1885/79728
dc.publisherAmerican Chemical Society
dc.sourceAnalytical Chemistry
dc.subjectKeywords: Chronometers; Computer simulation; Diffusion; Electrochemical electrodes; Polarization; Chronoamperometry; Concentration polarization; Disk electrodes; Amperometric sensors; accuracy; amperometry; article; calculation; chronoamperometry; concentration (pa
dc.titleDiffusion-controlled chronoamperometry at a disk electrode
dc.typeJournal article
local.bibliographicCitation.issue18
local.bibliographicCitation.lastpage6101
local.bibliographicCitation.startpage6100
local.contributor.affiliationMahon, Peter, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationOldham, Keith, Trent University
local.contributor.authoruidMahon, Peter, u4043257
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030102 - Electroanalytical Chemistry
local.identifier.ariespublicationMigratedxPub8111
local.identifier.citationvolume77
local.identifier.doi10.1021/ac051034y
local.identifier.scopusID2-s2.0-24944536653
local.type.statusPublished Version

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