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Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(ii) carbido complex

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Date

2020-07-14

Authors

Barnett, Harrison
Hill, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The reaction of [Rh2(μ-C)Cl2(PPh3)4] with 1,1'-bis(diphenylphosphino)ferrocene (dppf) affords the μ-carbido complex [Rh2(μ-C)Cl2(μ-dppf)2] which reacts with PhICl2 to provide a diamagnetic dirhodium(ii) carbido complex [Rh2(μ-C)Cl4(μ-dppf)2].

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Keywords

Citation

URI

http://hdl.handle.net/1885/217048

Collections

ANU Research Publications

Source

Chemical communications

Type

Journal article

Book Title

Entity type

Access Statement

Open Access

License Rights

DOI

10.1039/d0cc02349c

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10.1039_d0cc02349c.pdf (1.39 MB)

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