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Mixed-metal cluster chemistry. 26. Proclivity for "all-terminal" or "plane-of-bridging-carbonyls" ligand disposition in tungsten-triiridium clusters

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dc.contributor.authorUsher, Alistair
dc.contributor.authorDalton, Gulliver
dc.contributor.authorLucas, Nigel
dc.contributor.authorWaterman, Susan
dc.contributor.authorPetrie, Simon
dc.contributor.authorStranger, Robert
dc.contributor.authorWillis, Anthony
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-13T22:44:53Z
dc.date.available2015-12-13T22:44:53Z
dc.date.issued2004
dc.date.updated2015-12-11T10:18:16Z
dc.description.abstractReaction of WH(CO)3(η-C5Me5) with IrCl(CO)2(4-H2NC6H4Me) affords WIr3(μ-CO)3(CO)8 (η-C5Me5) in low yield. A structural study reveals a WIr2-centred plane of bridging carbonyls, in contrast to the crystal structure of WIr3(CO)11 (η-C5H5) (all-terminal
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/1885/79513
dc.publisherElsevier
dc.sourceJournal of Organometallic Chemistry
dc.subjectKeywords: bridged compound; carbon monoxide; carbonyl derivative; chromium; cyclopentadiene derivative; iridium complex; ligand; molybdenum; organometallic compound; phosphine; tungsten derivative; article; calculation; carbon nuclear magnetic resonance; controlled Carbonyl; Chromium; Cluster; Crystal structure; Cyclopentadienyl; Density functional theory; Fluxionality; Iridium; Molybdenum; Tungsten
dc.titleMixed-metal cluster chemistry. 26. Proclivity for "all-terminal" or "plane-of-bridging-carbonyls" ligand disposition in tungsten-triiridium clusters
dc.typeJournal article
local.bibliographicCitation.lastpage57
local.bibliographicCitation.startpage50
local.contributor.affiliationUsher, Alistair, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationDalton, Gulliver, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLucas, Nigel, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWaterman, Susan, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationPetrie, Simon, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationStranger, Robert, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidUsher, Alistair, u3937442
local.contributor.authoruidDalton, Gulliver, u3170420
local.contributor.authoruidLucas, Nigel, u9600762
local.contributor.authoruidWaterman, Susan, u3847237
local.contributor.authoruidPetrie, Simon, u9800071
local.contributor.authoruidStranger, Robert, u8708796
local.contributor.authoruidHumphrey, Mark, u9400918
local.contributor.authoruidWillis, Anthony, u8512028
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub7939
local.identifier.citationvolume689
local.identifier.doi10.1016/j.jorganchem.2003.09.026
local.identifier.scopusID2-s2.0-0347983787
local.type.statusPublished Version

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