Selective cleavage by acids of one metal-carbon σ-bond of a bis( ortho -platinated) triarylphosphane: a  31 P NMR  trans -influence series based on the unit Pt(κ 2 -C 6 H 3 -5-Me-2-PPh 2 )(PPh 2 -4-tol)

Bennett, Martin; Bhargava, Suresh Kumar; Priver, Steven H; Willis, Anthony

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Selective cleavage by acids of one metal-carbon σ-bond of a bis( ortho -platinated) triarylphosphane: a 31 P NMR trans -influence series based on the unit Pt(κ 2 -C 6 H 3 -5-Me-2-PPh 2 )(PPh 2 -4-tol)

Date

2008

Authors

Bennett, Martin

Bhargava, Suresh Kumar

Priver, Steven H

Willis, Anthony

Publisher

Wiley-VCH Verlag GMBH

Abstract

Supporting information for this article is available on the WWW under http://www.eurjic.org or from the author. Treatment of the bis(chelate) complex cis-[Pt(κ2-C6H3-5-Me-2-PPh 2)2] (1) with strong acids causes selective cleavage of one of the metal-aryl