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Dimetallapoly-yn-diylidynes: Ln M≡C-(C≡C)x -C≡MLn (x=0-4)

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dc.contributor.authorHill, Anthony
dc.contributor.authorManzano, Richard
dc.date.accessioned2020-12-14T02:16:03Z
dc.date.available2020-12-14T02:16:03Z
dc.date.issued2019-10-21
dc.description.abstractSynthetic routes to dimetallated Cx carbon wires in which two metals are separated by a linear carbon chain involving terminal metal-carbon triple bonds are described for the complexes [(Tp*)(CO)2 W≡C-(C≡C)n -C≡W(CO)2 (Tp*)] (Tp*=hydrotris(dimethylpyrazolyl)borate) where n=1, 3 or 4, joining the previously known examples with n=0, 1 and 2 to complete the series as models for linear carbyne C∞ .en_AU
dc.description.sponsorshipDP170102695 and DP190100723en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1433-7851en_AU
dc.identifier.urihttp://hdl.handle.net/1885/217171
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/1320..."The Accepted Version can be archived in a Non-Commercial Institutional Repository. 12 months embargo" from SHERPA/RoMEO site (as at 14/12/2020). This is the peer reviewed version of the following article: [Hill, Anthony F., and Richard A. Manzano. "Dimetallapoly‐yn‐diylidynes: LnM≡ C−(C≡ C) x− C≡ MLn (x= 0–4)." Angewandte Chemie International Edition 58.43 (2019): 15354-15357.], which has been published in final form at [https://dx.doi.org/10.1002/anie.201909550]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versionsen_AU
dc.publisherWileyen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695en_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723en_AU
dc.rights© 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheimen_AU
dc.sourceAngewandte Chemie International Editionen_AU
dc.subjectbis(carbyne)en_AU
dc.subjectcarbonen_AU
dc.subjectcarbyneen_AU
dc.subjecttungstenen_AU
dc.titleDimetallapoly-yn-diylidynes: Ln M≡C-(C≡C)x -C≡MLn (x=0-4)en_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Accessen_AU
local.bibliographicCitation.issue43en_AU
local.bibliographicCitation.lastpage15357en_AU
local.bibliographicCitation.startpage15354en_AU
local.contributor.affiliationHill, A., Research School of Chemistry, The Australian National Universityen_AU
local.contributor.affiliationManzano, R., Research School of Chemistry, The Australian National Universityen_AU
local.contributor.authoruidu4030185en_AU
local.identifier.citationvolume58en_AU
local.identifier.doi10.1002/anie.201909550en_AU
local.identifier.essn1521-3773en_AU
local.publisher.urlhttps://www.wiley.com/en-gben_AU
local.type.statusAccepted Versionen_AU

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