Poly(methimazolyl)borate Alkyne Complexes of Molybdenum and Tungsten

Hill, Anthony; Tshabang, Never; Willis, Anthony

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Poly(methimazolyl)borate Alkyne Complexes of Molybdenum and Tungsten

Date

2007

Authors

Hill, Anthony

Tshabang, Never

Willis, Anthony

Publisher

Wiley-VCH Verlag GMBH

Abstract

Synthetic routes are reported to complexes of the form [MI-(alkyne)(CO) {HnB(mt)4-n}] (mt = methimazolyl; n = 1, 2; M = Mo, W) through the reactions of alkyne complexes [WI2(HC≡CSiMe 3)2(CO)2] or [MI2(RC≡CR) 2(NCMe)(CO)] (M = Mo, W; R = Me, Ph) with t