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An unusual pendant-arm macrocycle formed by condensation of a cobalt(III) tripodal complex with methanal.

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Date

2002

Authors

Angus, Patricia
Geue, Rodney
Jensen, Niels
Larsen, Krebs
Qin, Chang
Sargeson, Alan

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The reaction of [Co(ten)]3+ {ten = 4,4′,4″-ethylidynetris(3-thiabutan-1-amine)} with methanal and base in acetonitrile or water led to the synthesis of an unusual pendant-arm macrocyclic complex, 8-(4′-ammonio-2′-thiabutyl)-8-methyl-1-oxa-6, 10-di

Description

Keywords

Keywords: Acetonitrile; Condensation; Polymers; Proteins; Synthesis (chemical); X ray crystallography; Methanal; Cobalt compounds

Citation

URI

http://hdl.handle.net/1885/72556

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

Restricted until

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