An unusual pendant-arm macrocycle formed by condensation of a cobalt(III) tripodal complex with methanal.
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Authors
Angus, Patricia
Geue, Rodney
Jensen, Niels
Larsen, Krebs
Qin, Chang
Sargeson, Alan
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Volume Title
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Royal Society of Chemistry
Abstract
The reaction of [Co(ten)]3+ {ten = 4,4′,4″-ethylidynetris(3-thiabutan-1-amine)} with methanal and base in acetonitrile or water led to the synthesis of an unusual pendant-arm macrocyclic complex, 8-(4′-ammonio-2′-thiabutyl)-8-methyl-1-oxa-6, 10-di
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Dalton Transactions