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Rationalizing the different products in the reaction of N2 with three-coordinate MoL3 complexes

Date

Authors

Christian, Gemma

Stranger, Robert

Yates, Brian F

Cummins, Christopher C

Publisher

Royal Society of Chemistry

Abstract

The reaction of N2 with three-coordinate MoL3 complexes is known to give rise to different products, N-MoL3, L 3Mo-N-MoL3 or Mo2L6, depending on the nature of the ligand L. The energetics of the different reaction pathways are compared for L = NH2, NMe2,

Keywords

Keywords: Chemical bonds; Exothermic reactions; Ligands; Molybdenum compounds; Reaction kinetics; Thermodynamic properties; Exothermicity; Ligand size; Metal-metal bonding; Reaction pathways; Metal complexes

URI

http://hdl.handle.net/1885/20798

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

DOI

10.1039/b701050h

Restricted until

2037-12-31

Downloads

File

Description

01_Christian_Rationalizing_the_different_2007.pdf (328.35 KB)

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