Organometallic complexes for nonlinear optics. 52. Syntheses, structural, spectroscopic, quadratic nonlinear optical, and theoretical studies of Ru(C 2 C 6 H 4 R-4)(κ 2 -dppf)(η 5 -C 5 H 5 ) (R = H, NO 2 )

Babgi, Bandar; Al-Hindawi, Ahmed; Moxey, Graeme; Abdul Razak, Fazira; Cifuentes, Marie; Kulasekera, Erandi; Stranger, Robert; Teshome, Ayele; Asselberghs, Inge; Clays, Koen Jan; Humphrey, Mark

Organometallic complexes for nonlinear optics. 52. Syntheses, structural, spectroscopic, quadratic nonlinear optical, and theoretical studies of Ru(C 2 C 6 H 4 R-4)(κ 2 -dppf)(η 5 -C 5 H 5 ) (R = H, NO 2 )

Date

2013

Authors

Babgi, Bandar

Al-Hindawi, Ahmed

Moxey, Graeme

Abdul Razak, Fazira

Cifuentes, Marie

Kulasekera, Erandi

Stranger, Robert

Teshome, Ayele

Asselberghs, Inge

Clays, Koen Jan

Publisher

Elsevier

Abstract

The synthesis of Ru(CCC6H4-4-NO2) (κ2-dppf)(η5-C5H5) (1) is reported, together with spectroscopic, X-ray structural, linear optical and quadratic nonlinear optical (NLO) studies of 1 and Ru(CCPh)(κ2- dppf)(η5-C5H5) (2), the last-mentioned using the hy