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Unprecedented Regio- and Stereoselective Conversion of 1-Cyclopropyl-3-ethoxy-cyclopentadienes to 3-(E)-Alkylidene-cyclopentenes

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dc.contributor.authorFlynn, Bernard
dc.contributor.authorde Meijere, Armin
dc.date.accessioned2015-12-13T23:20:22Z
dc.date.issued1999
dc.date.updated2015-12-12T09:02:53Z
dc.description.abstractCyclopropylalkynes 1 were converted into cyclopropyl-substituted 3- ethoxy-5-dimethylaminocyclopentadienes 4 via initially formed (β- dimethylaminoethenyl)carbene complexes 3 and their subsequent formal [3 + 2] cycloaddition to a second alkyne of type 1
dc.identifier.issn0022-3263
dc.identifier.urihttp://hdl.handle.net/1885/90671
dc.publisherAmerican Chemical Society
dc.sourceJournal of Organic Chemistry
dc.subjectKeywords: 1 cyclopropyl 3 ethoxycyclopentadiene derivative; alcohol; cyclopentadiene derivative; cyclopentene derivative; tetrahydrofuran; unclassified drug; article; catalysis; complex formation; hydrolysis; stereochemistry; stereoisomerism; synthesis
dc.titleUnprecedented Regio- and Stereoselective Conversion of 1-Cyclopropyl-3-ethoxy-cyclopentadienes to 3-(E)-Alkylidene-cyclopentenes
dc.typeJournal article
local.bibliographicCitation.lastpage404
local.bibliographicCitation.startpage400
local.contributor.affiliationFlynn, Bernard, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationde Meijere, Armin, University of Gottingen
local.contributor.authoruidFlynn, Bernard, u9515317
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationMigratedxPub21099
local.identifier.citationvolume64
local.identifier.doi10.1021/jo980938z
local.identifier.scopusID2-s2.0-0033593545
local.type.statusPublished Version

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