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Asymmetric Synthesis of a Tertiary Arsine by Nucleophilic Addition to a Chiral Phosphine-Stabilized Arsenium Salt

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Date

2008

Authors

Coote, Michelle
Krenske, Elizabeth
Porter, Keith
Weir, Michelle
Willis, Anthony
Zhou, Xiangting
Wild, Stanley (Bruce)

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

A new method for the asymmetric synthesis of As-chiral tertiary arsines is described. The addition at -95 °C of n-butyllithium to a dichloromethane solution of a phosphine-stabilized arsenium salt of the type (±)-[R 3P→AsMePh]PF6, where R3P is an enan

Description

Keywords

Keywords: Argon; Arsenic; Complexation; Dichloromethane; Electron transitions; Enantioselectivity; Ions; Nuclear magnetic resonance; Nuclear magnetic resonance spectroscopy; Oxygen; Phosphorus; Phosphorus compounds; Semiconducting indium gallium arsenide; Solid sol

Citation

URI

http://hdl.handle.net/1885/54278

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om8006272

Restricted until

2037-12-31

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01_Coote_Asymmetric_Synthesis_of_a_2008.pdf (266.42 KB)

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