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Cobalt cage complexes with N3S3 donor sets and differing cavity sizes: a novel macrobicyclic cage with a contracted cap

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Authors

Osvath, Peter
Sargeson, Alan
McAuley, A.
Mendelez, Rosa
Subramanian, S.
Zaworotko, M.
Broge, Louise

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American Chemical Society

Abstract

Treatment of the cobalt(III) complex of the hexadentate tripodal N3N3 ligand ten (4,4′,4″-ethylidynetris(3-thiabutan1-amine) with propanal and paraformaldehyde under basic conditions, followed by borohydride reduction and reoxidation of the metal cent

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Inorganic Chemistry

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2037-12-31