Metallaboratranes: Bis- and Tris(methimazolyl)borane Complexes of Group 9 Metal Carbonyls and Thiocarbonyls

Abstract

The iridium poly(methimazolayl)borane complexes [IrH(CE)(PPh3) {κ3-B,S,S-B(mt)2R}](Ir→B) (mt = methimazolyl = 2-mercapto-3-methylimidazol-l-yl; E = O, S; R = mt, H) are described in detail. For R = mt, these materials are elucidated as paradigms for th Show more