Metallaboratranes: Bis- and Tris(methimazolyl)borane Complexes of Group 9 Metal Carbonyls and Thiocarbonyls
Date
2010
Authors
Crossley, Ian R
Hill, Anthony
Willis, Anthony
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Publisher
American Chemical Society
Abstract
The iridium poly(methimazolayl)borane complexes [IrH(CE)(PPh3) {κ3-B,S,S-B(mt)2R}](Ir→B) (mt = methimazolyl = 2-mercapto-3-methylimidazol-l-yl; E = O, S; R = mt, H) are described in detail. For R = mt, these materials are elucidated as paradigms for th
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Keywords
Keywords: Alternative routes; Borane complexes; Borate complexes; Chlorinated solvent; Hydride abstraction; Metal carbonyl; Metallaboratranes; Phase conversion; Carbonylation; Dyes; Hysteresis motors; Iridium; Iridium compounds; Rhodium; Rhodium compounds
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Organometallics
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Journal article
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2037-12-31
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