Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Rearrangement of bis(alkylidynyl)phosphines to phosphaacyls

Simple item page
dc.contributor.authorColebatch, Annie
dc.contributor.authorHan, Yong-Shen
dc.contributor.authorHill, Anthony
dc.contributor.authorSharma, Manab
dc.contributor.authorShang, Rong
dc.contributor.authorWard, James
dc.date.accessioned2020-12-11T03:14:11Z
dc.date.available2020-12-11T03:14:11Z
dc.date.issued2017
dc.date.updated2020-11-23T11:01:00Z
dc.description.abstractA range of bis(alkylidynyl)phosphines RP{CRM(CO)2(Tp*)}2 (M =Mo, W; R = Cl, Ph, Cy; Tp* = hydrotris(dimethylpyrazolyl)borate) are obtained from the reactions of [M(RCLi)(CO)2(Tp*)] with Cl2PR or alternatively via the palladium(0)-mediated reactions of [W(RCBr)(CO)2(Tp*)] with RPH2 (R = Py, Cy). The complexes RP{CRW(CO)2(Tp*)}2 rearrange slowly (R = Cl) or on heating (R = Ph) to afford the isomeric phosphaacyls [W2(l:g1-C;g2-C,P-CCPR)(CO)4(Tp*)2].en_AU
dc.description.sponsorshipDP110101611 and DP130102598en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1359-7345en_AU
dc.identifier.urihttp://hdl.handle.net/1885/216846
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/18003..."The Accepted Version can be archived in a Non-Commercial Repository. 12 months embargo" from SHERPA/RoMEO site (as at 11/12/2020).en_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP110101611en_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP130102598en_AU
dc.rights© The Royal Society of Chemistry 2017en_AU
dc.sourceChemical Communicationsen_AU
dc.titleRearrangement of bis(alkylidynyl)phosphines to phosphaacylsen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Accessen_AU
local.bibliographicCitation.issue11en_AU
local.bibliographicCitation.lastpage1835en_AU
local.bibliographicCitation.startpage1832en_AU
local.contributor.affiliationColebatch, Annie, College of Science, ANUen_AU
local.contributor.affiliationHan, Yong-Shen, College of Science, ANUen_AU
local.contributor.affiliationHill, Anthony, College of Science, ANUen_AU
local.contributor.affiliationSharma, Manab, College of Science, ANUen_AU
local.contributor.affiliationShang, Rong, College of Science, ANUen_AU
local.contributor.affiliationWard, James, College of Science, ANUen_AU
local.contributor.authoruidColebatch, Annie, u4213195en_AU
local.contributor.authoruidHan, Yong-Shen, u4847101en_AU
local.contributor.authoruidHill, Anthony, u4030185en_AU
local.contributor.authoruidSharma, Manab, u4939765en_AU
local.contributor.authoruidShang, Rong, u4469159en_AU
local.contributor.authoruidWard, James, u4431856en_AU
local.description.notesImported from ARIESen_AU
local.identifier.absfor030503 - Organic Chemical Synthesisen_AU
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciencesen_AU
local.identifier.ariespublicationu5247729xPUB56en_AU
local.identifier.citationvolume53en_AU
local.identifier.doi10.1039/c6cc09764ben_AU
local.identifier.scopusID2-s2.0-85011340358
local.identifier.thomsonID000395590800013
local.publisher.urlhttp://pubs.rsc.org/en/Journals/JournalIssues/CCen_AU
local.type.statusAccepted Versionen_AU

Downloads

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
Rearrangement of Bis(alkylidynyl)phosphines.pdf
Size:
2.13 MB
Format:
Adobe Portable Document Format
Description:
Download

Collections

ANU Research Publications

DSpace software copyright © 2002-2026 LYRASIS

abcd