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Installation of a ratchet tooth and pawl to restrict rotation in a cyclodextrin rotaxane

Date

Authors

Onagi, Hideki

Blake, Christopher

Easton, Christopher

Lincoln, Stephen F

Publisher

Wiley-VCH Verlag GMBH

Abstract

Eight new [2]rotaxanes have been prepared, incorporating an α-cyclodextrin as the rotor, a stilbene as the axle, and trinitrophenyl substituents as capping groups. Strategies have been devised to elaborate these by linking the rotor to the axle, to produ

Keywords

Keywords: Axles; Polyamides; Rotation; Rotors; Capping groups; Ratchet tooth; Aromatic compounds; alpha cyclodextrin; cyclodextrin; dendrimer; rotaxane; stilbene; succinimide derivative; trinitrophenyl; article; chemical composition; chemical structure; device; mol Cyclodextrins; Molecular devices; Molecular dynamics; NMR spectroscopy; Rotaxanes

URI

http://hdl.handle.net/1885/88640

Collections

ANU Research Publications

Source

Chemistry, A European Journal

Type

Journal article

DOI

10.1002/chem.200305280