Bis(1,3-di-tert-butylimidazolin-2-iminato) Titanium Complexes as Effective Catalysts for the Monodisperse Polymerization of Propylene

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Date

2012

Authors

Sharma, Manab
Yameen, Haneen Simaan
Tumanskii, Boris
Filimon, Sabina-Alexandra
Tamm, Matthias
Eisen, Moris S.

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The use of bis(1,3-di-tert-butylimidazolin-2-iminato) titanium dichloride (1) and dimethyl (2) complexes in the polymerization of propylene is presented. The complexes were activated using different amounts of methylalumoxane (MAO), giving in each case a

Description

Keywords

Keywords: Chain transfer; Cocatalyst; Dormant species; MALDI-TOF; Methyl complexes; Methylalumoxane; Monodisperse; Narrow molecular weight distributions; Pentafluorophenyl; Physical methods; Plausible mechanisms; Titanium complexes; Titanium dichloride; Trityl radi

Citation

URI

http://hdl.handle.net/1885/63309

Collections

ANU Research Publications

Source

Journal of the American Chemical Society

Type

Journal article

Book Title

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DOI

10.1021/ja3071545

Restricted until

2037-12-31

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