Reactions of [Mo(≡CBr)(CO) 2 {HB(pzMe 2 ) 3 }] (pz = pyrazol-1-yl) with Amines: Synthesis of Amino, Pyridinium, and Thiolato Carbyne Complexes

Cordiner, Richard; Hill, Anthony; Wagler, Jorg

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Reactions of [Mo(≡CBr)(CO) 2 {HB(pzMe 2 ) 3 }] (pz = pyrazol-1-yl) with Amines: Synthesis of Amino, Pyridinium, and Thiolato Carbyne Complexes

Date

2008

Authors

Cordiner, Richard

Hill, Anthony

Wagler, Jorg

Publisher

American Chemical Society

Abstract

The reactions of the bromocarbyne complex [Mo(≡CBr)(CO) 2[HB(pzMe2)3}] (pz = pyrazol-1-yl) with a range of secondary and heterocyclic amines have been investigated and found in each case to proceed via simple nucleophilic halide substitution to provide