Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

A chemoenzymatic total synthesis of the protoilludane aryl ester (+)-Armillarivin

Date

Authors

Schwartz, Brett

Matousova, Eliska

White, Richard

Banwell, Martin

Willis, Anthony

Publisher

American Chemical Society

Abstract

The title natural product, 1, has been synthesized in 20 steps from the enantiomerically pure cis-1,2-dihydrocatechol 2, itself obtained through the whole-cell biotransformation of toluene. The pivotal steps in the reaction sequence involve a Diels-Alder

Keywords

Keywords: armillarivin; biological product; cyclopentane derivative; cyclopentenone; ester; protoilludane; sesquiterpene; article; chemical structure; chemistry; stereoisomerism; synthesis; Biological Agents; Cyclopentanes; Esters; Molecular Structure; Sesquiterpen

URI

http://hdl.handle.net/1885/61959

Collections

ANU Research Publications

Source

Organic Letters

Type

Journal article

DOI

10.1021/ol400583c

Restricted until

2037-12-31

Downloads

File

Description

01_Schwartz_A_chemoenzymatic_total_2013.pdf (449.72 KB)