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The Palladium-Catalyzed Intramolecular Alder-Ene Reactions of O- and N-Linked 1,6-Enynes Incorporating Triethylsilyl Capping Groups

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dc.contributor.authorNugent, Jeremy
dc.contributor.authorMatoušová, Eliška
dc.contributor.authorBanwell, Martin
dc.contributor.authorWillis, Anthony
dc.date.accessioned2021-01-06T04:29:38Z
dc.date.issued2017
dc.date.updated2020-11-23T11:19:10Z
dc.description.abstractA series of O- and N-linked 1,6-enynes (e.g., 11) have been prepared with each subjected to a palladium-catalyzed intramolecular Alder-ene (IMAE) reaction, thus producing the isomeric and cyclic 1,4-diene (e.g., 12). These processes proceed most effectively when a triethylsilyl group is attached to the alkyne moiety and so generating alkenylsilanes that can be manipulated in various useful ways, including via iododesilylation (to give, for example, iodoalkene 62).en_AU
dc.description.sponsorshipWe [thank] the Australian Research Council and the Institute of Advanced Studies for financial support. J.N. is the grateful recipient of a PhD Scholarship provided by the Australian Government.en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn0022-3263en_AU
dc.identifier.urihttp://hdl.handle.net/1885/219196
dc.language.isoen_AUen_AU
dc.publisherAmerican Chemical Societyen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP170100926en_AU
dc.rights© 2017 American Chemical Societyen_AU
dc.sourceJournal of Organic Chemistryen_AU
dc.titleThe Palladium-Catalyzed Intramolecular Alder-Ene Reactions of O- and N-Linked 1,6-Enynes Incorporating Triethylsilyl Capping Groupsen_AU
dc.typeJournal articleen_AU
local.bibliographicCitation.issue23en_AU
local.bibliographicCitation.lastpage12589en_AU
local.bibliographicCitation.startpage12569en_AU
local.contributor.affiliationNugent, Jeremy, College of Science, ANUen_AU
local.contributor.affiliationMatousova, Eliska, College of Science, ANUen_AU
local.contributor.affiliationBanwell, Martin, College of Science, ANUen_AU
local.contributor.affiliationWillis, Anthony, College of Science, ANUen_AU
local.contributor.authoruidNugent, Jeremy, u4692164en_AU
local.contributor.authoruidMatousova, Eliska, u5228770en_AU
local.contributor.authoruidBanwell, Martin, u9500594en_AU
local.contributor.authoruidWillis, Anthony, u8512028en_AU
local.description.embargo2037-12-31
local.description.notesImported from ARIESen_AU
local.identifier.absfor030502 - Natural Products Chemistryen_AU
local.identifier.ariespublicationa383154xPUB8977en_AU
local.identifier.citationvolume82en_AU
local.identifier.doi10.1021/acs.joc.7b02355en_AU
local.identifier.scopusID2-s2.0-85036620614
local.publisher.urlhttp://pubs.acs.org/journal/joceah/about.htmlen_AU
local.type.statusPublished Versionen_AU

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