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An expanded cavity hexaamine cage for copper(II)

Date

Authors

Bernhardt, Paul

Bramley, Richard

Geue, Rodney

Ralph, Stephen F

Sargeson, Alan

Publisher

Royal Society of Chemistry

Abstract

The crystal structure of the bicyclic hexaamine complex [Cu(fac-Me 5-tricosane-N6)](ClO4)2· H2O (fac-Me5-tricosane-N6 = facial-1,5,9,13,20-pentamethyl-3,7,11,15,18,22-hexaazabicyclo[7.7.7]tricosane) at 100 K defines an apparently tetragonally compressed

Keywords

Keywords: Amines; Crystal structure; Cyclic voltammetry; Electron spin resonance spectroscopy; Encapsulation; Ligands; Expanded cage ligand; Hexaamine; Interconversion; Copper

URI

http://hdl.handle.net/1885/25216

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

DOI

10.1039/b617153b

Restricted until

2037-12-31

Downloads

File

Description

01_Bernhardt_An_expanded_cavity_hexaamine_2007.pdf (168.21 KB)

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